Amorphous ferroelectric thin film energy storage

How can flexible ferroelectric thin films improve energy storage properties?

Moreover, the energy storage properties of flexible ferroelectric thin films can be further fine-tuned by adjusting bending angles and defect dipole concentrations, offering a versatile platform for control and performance optimization.

What is the recoverable energy storage density of PZT ferroelectric films?

Through the integration of mechanical bending design and defect dipole engineering, the recoverable energy storage density of freestanding PbZr 0.52 Ti 0.48 O 3 (PZT) ferroelectric films has been significantly enhanced to 349.6 J cm −3 compared to 99.7 J cm −3 in the strain (defect) -free state, achieving an increase of ≈251%.

Which ferroelectric materials improve the energy storage density?

Taking PZT, which exhibits the most significant improvement among the four ferroelectric materials, as an example, the recoverable energy storage density has a remarkable enhancement with the gradual increase in defect dipole density and the strengthening of in-plane bending strain.

Are ferroelectric thin-film capacitors flexible?

Advances in flexible electronics are driving the development of ferroelectric thin-film capacitors toward flexibility and high energy storage performance.

What are the characteristics of ferroelectric thin films?

Ferroelectric thin films exhibit tensile strain, strain gradient, and defect dipole states. b) The double-well potential of Landau free energy with the strain (defect)-free state (blue curve) and with strain and strain gradient engineering as well as defect engineering (red curve).

What is a freestanding ferroelectric film?

Freestanding ferroelectric films, such as BaTiO 3 (BTO) and BiFeO 3 (BFO), obtained through methods like wet etching or laser lift-off, can be folded nearly 180° without damage and exhibit remarkable piezoelectric, flexoelectric, and flexo-photovoltaic effects.