Energy storage plus ten radicals

Can organic radicals be used as redox-active materials for electrochemical energy storage?

Recently, researchers have begun to explore the use of stable organic radicals, both discrete molecules and radical-bearing polymers, as redox-active materials for electrochemical energy storage , , , , , , , , , .

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What types of organic radicals are used for energy storage?

Prominent and promising classes of stable organic radicals for energy storage include nitroxides , , , , phenoxyls , , , , , , , , , and verdazyls , .

What are the electrochemical aspects of persistent radicals?

This paper reviews the electrochemical aspects of persistent radicals and the corresponding macromolecules, radical polymers. Radical structures and their redox reactions are introduced, focusing on redox potentials, bistability, and kinetic constants for electrode reactions and electron self-exchange reactions.

What are radical structures and their redox reactions?

Radical structures and their redox reactions are introduced, focusing on redox potentials, bistability, and kinetic constants for electrode reactions and electron self-exchange reactions. Unique charge transport and storage properties are also observed with the accumulated form of redox sites in radical polymers.

Are persistent radicals reversible redox reactions?

The molecules also display fast, reversible redox reactions, which have attracted particular attention for energy conversion and storage devices. This paper reviews the electrochemical aspects of persistent radicals and the corresponding macromolecules, radical polymers.